| SECTION 4: |
FIRE AND EXPLOSION DATA |
| FLAMMABILITY: |
No |
| IF
YES, UNDER WHICH CONDITIONS: |
|
| MEANS OF EXTINCTION: |
As
appropriate for the surrounding fire. |
| SPECIAL PROCEDURES: |
Use
protective clothing suitable for acids and self-contained breathing apparatus. |
| FLASHPOINT (°C) AND METHOD: |
None |
| UPPER EXPLOSION LIMIT (% BY VOLUME) |
NA |
| LOWER EXPLOSION LIMIT (% BY VOLUME) |
NA |
| AUTO IGNITION TEMPERATURE (°C): |
NA |
| TDG FLAMMABILITY CLASSIFICATION: |
NA |
| HAZARDOUS COMBUSTION PRODUCTS: |
Hydrogen
chloride gas and other toxic fumes. |
| EXPLOSION DATA |
|
|
UNUSUAL FIRE & EXPLOSION HAZARD: |
Flammable
hydrogen gas is generated by reaction with many metals. |
|
SENSITIVITY TO IMPACT: |
NA |
|
SENSITIVITY TO STATIC DISCHARGE: |
NA |
| SECTION 5: |
REACTIVITY DATA |
| CHEMICALLY STABLE: |
Stable
under normal conditions. |
| IF NO, UNDER WHICH CONDITIONS: |
Toxic
acid fumes are generated at high temperatures. |
| COMPATIBILITY WITH OTHER SUBSTANCES: |
No |
| IF NO, WHICH ONES? |
Base
metals, metal oxides, alkaline materials may react violently producing hydrogen
gas and toxic fumes. |
| REACTIVITY, AND UNDER WHAT CONDITIONS: |
Toxic
fumes are generated by reaction with alkalies, oxidants, and many metals. |
| HAZARDOUS DECOMPOSITION PRODUCTS: |
Hydrogen
chloride fumes, hydrogen gas. |
| SECTION 6: |
TOXICOLOGICAL PROPERTIES |
| ROUTE OF ENTRY: |
|
|
SKIN CONTACT: |
Yes |
|
SKIN ABSORPTION: |
Yes |
|
EYE CONTACT: |
Yes |
|
INHALATION ACUTE: |
Yes |
|
INHALATION CHRONIC: |
Yes |
|
INGESTION: |
Yes |
| EFFECTS OF ACUTE EXPOSURE TO MATERIAL: |
Can
cause severe burns to eyes, skin, mucous membranes and upper respiratory tract. |
| Effects of chronic exposure: |
Vapour causes tooth erosion,
nose and gum bleeding, skin inflammation. |
| LD OF MATERIAL: |
NE |
| LC OF MATERIAL: |
NE |
| EXPOSURE LIMIT OF MATERIAL: |
Hydrochloric
Acid: TLV 5 ppm. Phosphoric Acid: TLV 1 mg/m (as mist). |
| IRRITANCY OF MATERIAL: |
Severe
irritant |
| SENSITIZING CAPABILITY OF MATERIAL: |
Not
known |
| CARCINOGENICITY OF MATERIAL: |
Not
known |
| REPRODUCTIVE EFFECTS OF MATERIAL: |
Not
known |
| SYNERGISTIC MATERIALS: |
Not
known |
| SECTION 7: |
PREVENTIVE MEASURES |
| PERSONAL PROTECTIVE EQUIPMENT: |
Wear
gloves and goggles when handling very small quantities during normal use. Use appropriate respirator if misty
conditions prevail. Wear boots and
apron in addition to face shields and gloves if handling large quantities. |
| GLOVES (SPECIFY): |
Neoprene,
PVC, rubber. |
| RESPIRATORY (SPECIFY): |
Self-contained
breathing apparatus if vapour or mist is present or if TLV is exceeded. |
| EYE(SPECIFY): |
Splash
proof safety goggles or full face shield. |
| FOOTWEAR (SPECIFY): |
Impervious
boots if handling large quantities. |
| CLOTHING (SPECIFY): |
Neoprene,
PVC or rubber apron if handling large quantities. |
| OTHER (SPECIFY) |
Eye
bath, showers. |
| ENGINEERING CONTROLS: |
Provide
mechanical ventilation of confined spaces. |
| LEAK AND SPILL PROCEDURE: |
Zone off
contaiminated area. Ventilate. Wear protective gear. Only adequately trained persons should
participate in the clean up. For small
spills neutralize with soda ash or lime and wash down with large quantities of
water. Alternatively, absorb
vermiculite, dry sand or a similar material.
Shovel into Containers for disposal. |
| WASTE DISPOSAL: |
Dispose
of through a licensed waste disposal facility. |
| HANDLING PROCEDURES & EQUIPMENT: |
Use
trained personnel only. Wear suitable
protective equipment. |
| STORAGE REQUIREMENTS: |
Store
in a separate, well ventilated, cool, dry area. Keep containers tightly closed when not in use. |
| SPECIAL SHIPPING INFORMATION: |
Apply
“corrosive” labels. |